You’d be surprised at how different a RAW file of sunset photo looks compared to the final edit (and to what the view was like in real life.) For this type of shot, I typically underexpose so that I can retain the highlight in the sky and then pull back shadows, temperature, colors, etc. in post processing. See my whole lightroom process for this photo below! And please leave a comment if you have any questions.
How to Edit a Sunset Photo in Lightroom in Under 90 Seconds | Seattle Adventure & Elopement Photographer